Identification
Name		1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
Synonyms		[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane; Pd(dppf)Cl2 · CH2Cl2 Pd(dppf)Cl2 · DCM [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1) C35H30Cl4FeP2Pd
Molecular Structure
Molecular Formula		C35H30Cl4FeP2Pd
Molecular Weight		816.64
CAS Registry Number		95464-05-4
Properties
Pd content		13%
Appearance		Orange red powder
Specification		Analytical pure
Application		Catalyst, Carbonylation, Cross-coupling reaction, Suzuki reaction
Safety Data
Hazard Symbols		Xn
Risk Code		20/21/22-36/37/38-40-67-48/20/22
Safety Description		23-24/25-26-36/37

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Application:

1,1' -bis (Diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is an organometallic compound that can be used as a noble metal catalyst for carbonylation reactions, cross-coupling reactions, Suzuki reaction.

Preparation of 1,1' -bis (Diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex:

Step 1. Dissolve 2.00 grams of sodium palladium chloride in 30mL of anhydrous ethanol to obtain the ethanol solution of sodium palladium chloride;

Step 2: Dissolve 4.15 grams of 1,1 '-bis (diphenylphosphine) ferrocene in 41mL dichloromethane to obtain 1,1' -bis (diphenylphosphine) ferrocene dichloromethane solution;

Step 3. Under stirring conditions, add the ethanol solution of sodium palladite chloride in step 1 to dichloromethane solution of 1, 1 '-bis (diphenylphosphine) ferrocene in step 2. Stir and react for 1h at 25℃. 1 '-bis (diphenylphosphine) ferrocene] dichloromethane palladium chloride complex crystal, yield 90.46%.

In this method, the target product [1,1 '-bis (diphenylphosphine) ferrolocene] palladium dichloromethane complex was synthesized directly with dichloromethane as the solvent in one step, eliminating the synthesis process of precursor PDCl2 (DPPF). The reaction process is simple, the synthesis cycle is short, easy to operate, and the purity of the synthesized product is 99.4%. The yield was 90.46%.