1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex, 95464-05-4 , Pd(dppf)Cl2 · CH2Cl2
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex, 95464-05-4 , Pd(dppf)Cl2 · CH2Cl2
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex, 95464-05-4 , Pd(dppf)Cl2 · CH2Cl2
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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
Identification
Name
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
Synonyms

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane;

Pd(dppf)Cl2 · CH2Cl2

Pd(dppf)Cl2 · DCM

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1)

C35H30Cl4FeP2Pd


Molecular Structure
95464-05-4

Molecular Formula
C35H30Cl4FeP2Pd
Molecular Weight
816.64
CAS Registry Number
95464-05-4
Properties
Pd content
13%
Appearance
Orange red powder
Specification
Analytical pure
Application
Catalyst, Carbonylation, Cross-coupling reaction, Suzuki reaction
Safety Data
Hazard Symbols
Xn
Risk Code

20/21/22-36/37/38-40-67-48/20/22
Safety Description

23-24/25-26-36/37

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Application:

1,1' -bis (Diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is an organometallic compound that can be used as a noble metal catalyst for carbonylation reactions, cross-coupling reactions, Suzuki reaction.


Preparation of 1,1' -bis (Diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex:

Step 1. Dissolve 2.00 grams of sodium palladium chloride in 30mL of anhydrous ethanol to obtain the ethanol solution of sodium palladium chloride;

Step 2: Dissolve 4.15 grams of 1,1 '-bis (diphenylphosphine) ferrocene in 41mL dichloromethane to obtain 1,1' -bis (diphenylphosphine) ferrocene dichloromethane solution;

Step 3. Under stirring conditions, add the ethanol solution of sodium palladite chloride in step 1 to dichloromethane solution of 1, 1 '-bis (diphenylphosphine) ferrocene in step 2. Stir and react for 1h at 25℃. 1 '-bis (diphenylphosphine) ferrocene] dichloromethane palladium chloride complex crystal, yield 90.46%.

In this method, the target product [1,1 '-bis (diphenylphosphine) ferrolocene] palladium dichloromethane complex was synthesized directly with dichloromethane as the solvent in one step, eliminating the synthesis process of precursor PDCl2 (DPPF). The reaction process is simple, the synthesis cycle is short, easy to operate, and the purity of the synthesized product is 99.4%. The yield was 90.46%.

1,1-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is a highly efficient and widely used catalyst in organic synthesis. It is also known as Pd(dppf)Cl2.CH2Cl2, and is a bright orange crystalline powder that is soluble in organic solvents like dichloromethane.

This complex is formed by the reaction of PdCl2 with 1,1-Bis(diphenylphosphino)ferrocene (dppf) in the presence of dichloromethane. It has a unique molecular structure that allows it to catalyze a wide range of organic reactions, including cross-coupling reactions, hydrogenations, and oxidative couplings.

The advantages of using 1,1-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex as a catalyst include its high catalytic activity, selectivity, and stability. It also has a long lifespan, making it cost-effective for large-scale production.

If you're interested in purchasing 1,1-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex, you can contact UIV Chem. As a future-oriented scientific enterprise, UIV Chem is committed to providing high-quality fine chemicals and catalysts for sustainable development solutions. With our large R&D centers, 1k grade clean workshop, and team of international experts, we can guarantee the quality and reliability of our products.

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