[1,1′-Bis(Diphenylphosphino) Ferrocene] Dichloropalladium(II) , 72287-26-4 , Pd(Dppf)Cl2
[1,1′-Bis(Diphenylphosphino) Ferrocene] Dichloropalladium(II) , 72287-26-4 , Pd(Dppf)Cl2
[1,1′-Bis(Diphenylphosphino) Ferrocene] Dichloropalladium(II) , 72287-26-4 , Pd(Dppf)Cl2
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dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) complex;


(II)dichloromethane adduct;
[1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex;


Molecular Structure

Molecular Formula
Molecular Weight
CAS Registry Number
Palladium content

air and moisture sensitive
Analytical pure
Catalyst, Carbonylation, Cross-coupling reaction, Suzuki reaction
Melting point
275-280 ºC
Orange red powder

Soluble in dichloromethane.
Safety Data
Hazard Symbols
Risk Codes
Safety Description

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Uses:

[1,1'-Bis(diphenylphosphino)ferrocene]palladium dichloride (PdCl2(dppf)) as a catalyst is mainly used to catalyze the cross-coupling reaction. Similar to other Pd(II) and Ni(II) complexes, PdCl2(dppf) can effectively catalyze the cross-coupling reaction between halogenated olefins, halogenated aromatic hydrocarbons or trifluoromethanesulfonate aromatic hydrocarbons and Grignard reagents. Achieve the formation of carbon-carbon bonds.

Catalyst for carbonylation reaction, cross-coupling reaction, Suzuki reaction.C-C and C-N coupling reaction catalyst.

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Preparation:

A preparation method of 1,1'-bis(diphenylphosphino)ferrocene palladium dichloride II (dppfPdCl2), including the following steps:

(A) Add palladium chloride to concentrated hydrochloric acid and heat to 40-80℃ to dissolve. The amount of hydrochloric acid is 0.2-1.0 times the mass of palladium chloride. Add ethanol to dilute Chemicalbook to release. The amount of ethanol is 10- of the mass of palladium chloride. 50 times;

(B) Add bisdiphenylphosphinoferrocene (dppf) of 3.0-5.0 times the mass of palladium chloride to the tetrahydrofuran solution, and heat to 40-80°C until it dissolves. The amount of tetrahydrofuran is 20% of the mass of palladium chloride. -30 times;

(C) Add the solution obtained in step (a) dropwise to the solution obtained in step (b), keep it at 45-80°C for 0.5-3h after dropping, then cool, filter, wash, and vacuum dry to obtain 1, 1'-Bis(diphenylphosphino)ferrocene palladium dichloride II red crystals.

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