Triruthenium Dodecacarbonyl，15243-33-1，C12O12Ru3

Identification
Name		Triruthenium dodecacarbonyl
Synonyms		Ru3(CO)12 Trirutheniumdodecarbonyl(DCR) dodecacarbonyltri-rutheniutriangulo RUTHENIUM CARBONYL DODECACARBONYLTRIRUTHENIUM
Molecular Structure
Molecular Formula		C12O12Ru3
Molecular Weight		639.33
CAS Registry Number		15243-33-1
EINECS		239-287-4
Properties
Melting point		150 °C
Purity		>99%
Ruthenium content		47%min
Appearance		Orange powder
Solubility		Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.
Safety Data
Hazard Symbols		F;Xn
Risk Codes		R11;R20
Safety Description		24/25
Transport Information		1325

Triruthenium dodecacarbonyl purpose:

The precursor of the carbonyl group and the H-transfer catalyst. Used for the reductive carbonylation of aromatic nitro complexes to carbamate.

Triruthenium dodecacarbonyl application areas:

The main application areas of triruthenium dodecacarbonyl are as follows: 1. As a catalyst for the [3+2+1] carbonyl cycloaddition reaction of silylacetylene compounds with α, β-unsaturated ketones, α can be obtained in high yields. -Pyranone. 2. The precursor of carbonyl cluster compound and hydrogen transfer catalyst. 3. Used in the reductive carbonylation reaction of aromatic nitro compounds to generate carbamate. 4. The phosphine-stabilized carbonyl cluster compound has been attached to the oxide support. 5. It is used to obtain improved catalytic effect in the allyl amination reaction of unactivated olefins by aromatic nitro compounds.