Allyl methacrylate_CAS:96-05-9
Allyl methacrylate_CAS:96-05-9
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Allyl methacrylate_CAS:96-05-9

Identification
Name
Allyl methacrylate
Synonyms

methylacrylic acid-allyl ester;

2-Methyl-2-propenyl 2-propenoate

prop-2-enyl 2-methylprop-2-enoate

Acryester A

prop-2-enyl 2-methylprop-2-enoate

copyRight
Molecular Structure
96-05-9

Molecular Formula
C7H10O2
Molecular Weight
126.15
CAS Registry Number
96-05-9
EINECS
202-473-0
Properties
Density
0.93
Melting point
-65 ºC
Boiling point
144 ºC
Refractive index
1.435-1.437
Flash point
37 ºC
Water solubility
4 g/L (20 ºC)
Safety Data
Hazard Symbols
T;N
Risk Codes
R10;R21/22;R23;R50
Safety Description
S36/37;S45;S61
Transport Information
UN 2929
Uses of allyl methacrylate:

It is widely used as a comonomer, grafting monomer and crosslinking agent for tooth repair in the preparation of plexiglass.

Allyl methacrylate is an important crosslinking agent, which can provide the second stage of effective bifunctional crosslinking, with good chemical resistance, impact strength, adhesion, hardness and low water shrinkage. Used in dental materials, industrial paints, organic silicon intermediates, light stabilizers, optical polymers, elastomers and some vinyl and acrylic polymer systems.


Production method of allyl methacrylate:

It can be obtained by the reaction of acrylamide and allyl alcohol under the action of concentrated acid and H2O2, or it can be obtained by transesterification of allyl acetate and methyl methacrylate. It can also be prepared by reacting methacrylic acid with allyl alcohol, using p-toluenesulfonic acid as a catalyst and refluxing in the presence of the polymerization inhibitor hydroquinone. The water produced is continuously removed during the reaction. After the reaction is completed, the excess is recovered by fractional distillation. Allyl alcohol, the product is purified by distillation under reduced pressure.



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